Cassane-type diterpenoids from the genus Caesalpinia

نویسندگان

  • R. A. Dickson
  • T. C. Fleischer
  • P. J. Houghton
چکیده

Caesalpinia is the name of a genus of enormous size and of ancient origin. It is named after the Italian naturalist, Andreas Caesalpino, of Arezzo (1519-1603). He was also a botanical collector, systematist and philosopher, chief physician to Pope Clement VIII, and a professor of medicine and botany in Pisa and Rome.[1] Caesalpinia consists of about 200 species, consisting of shrubs, tall climbers, small and tall trees, mostly armed with spines and curves, hooked, sharp thorns and rarely unarmed. Their leaves are bipinnate, lacy, and attractive, while the leaflets are few to many, opposite, rarely alternate, small or large, herbaceous or leathery. The flowers are yellow, red, or variegated, showy, handsome, medium to large and are multiflowered. Finally, the pods are variable, often prickly, flat, straight or beaked.[2,3]

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

New cassane-type diterpenoids from Caesalpinia bonduc.

Six new cassane diterpenoids, named caesalls H-M (1-6), were isolated from the seed kernels of Caesalpinia bonduc. Their structures were elucidated on the basis of spectroscopic analysis, mainly NMR and MS. The absolute configurations of compounds 1 and 3 were determined by a single-crystal X-ray study using a mirror CuKα radiation and circular dichroism (CD) spectra, respectively. None of the ...

متن کامل

A new cassane diterpenoid from the seeds of Caesalpinia decapetala.

Phytochemical investigation on the seeds of Caesalpinia decapetala led to the isolation of a new cassane diterpenoid with an unusual O bridge between C-19 and C-20, named phanginin Q (1), together with three known cassane diterpenoids, caesaljapin (2), caesaldekarin A (3), and caesaldekarin B (4). The structure of the new compound was elucidated by spectroscopic methods, including (1)H NMR, (13...

متن کامل

Cytotoxic and Pro-Apoptotic Effects of Cassane Diterpenoids from the Seeds of Caesalpinia sappan in Cancer Cells.

The chemical study on the seeds of Caesalpinia sappan led to the isolation of five new cassane diterpenoids, phanginins R‒T (1-3) and caesalsappanins M and N (4 and 5), together with seven known compounds 6-12. Their structures were elucidated on the basis of NMR and HRESIMS analyses. The absolute configurations of compounds 1 and 4 were determined by the corresponding CD spectra. All the isola...

متن کامل

New Cassane Diterpenoids from Caesalpinia sappan and their Antiplasmodial Activity.

One new cassane diterpene possessing an unusual N bridge between C-19 and C-20 named caesalsappanin R (1), as well as another new diterpene caesalsappanin S (2), were isolated from the seeds of Caesalpinia sappanwith methanol extract. Their structures were determined by spectroscopic analysis and examined alongside existing data from prior studies. Their biological activities were profiled by t...

متن کامل

Seven new cassane furanoditerpenes from the seeds of Caesalpinia minax.

A bioassay-guided study led to the isolation of seven new cassane furanoditerpenes, designated as spirocaesalmin B (1), caesalpinin M1 (2), caesalpinin M2 (3), caesalmin E1 (4), caesalmin E2 (5), caesalmin E3 (6), caesalpinin F1 (7) and three known compounds neocaesalpin A(8), neocaesalpin L(9), neocaesalpin L1(10) from the seeds of Caesalpinia minax Hance. Compound structures were determined o...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2014